Preformance wise, I don't think anything's changed.
Here's a short list of what's new since 5.0:
Quote:
5.02 New Stuff:
1. command line parameters are used.
5.00 New stuff:
Add - Big packets" setting
Add - checkpoint interval
Add - WU type - no preference/standard/no-deadline
Fix - Logs are no longer deleted every run by the GUI.
And all the rest of the 5.00 stuff of course 
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My little iBook has been chugging away for almost three days on this one protein! (It's p265_h2o or "Insights into Nucleic Acid Conformational Dynamics from Massively
Parallel Stochastic Simulations") Yikes!
Have you guys ever looked up the protein descriptions?
Deep stuff!
Check out the list here.